Well, as you say, Adamantium is dense and rare. It's also very durable and hard.
The name does imply that it's an element, but the truth is, if it were an as of yet undiscovered element, it would almost certainly be a lot rarer. What I like to think is that it's something we know of, but under a different name.
All though the name implies that it's an elemental metal, we shouldn't write off the possibility of it being some form of alloy either. Or possibly not a metal at all - after all, Helium's name would imply the same, but it's clearly not.
The closest real world equivalents are probably Elements 73-77: Tantalum, Tungsten, Rhenium, Osmium, and Iridium.
All dense, hard and pricey, these fit the bill pretty well. They vary between ductile (tantalum & rhenium) and brittle (tungsten, osmium and iridium); can be alloyed in various combinations with one another combining properties; have hard and dense carbides; and are highly corrosion resistant.
For that reason, my best guess is that it's one of those elements, an alloy of them, or perhaps even some form of carbide.
Plasteel is a bit harder to work out, and it depends on whether the plas is from "Plasma" or "Plastic"
I would suggest that it's NOT plastic, as Armaplas is already defined as a metal/plastic composite.
Thermoplas... no idea. Some heat resistant plastic? But that doesn't really explain why it would be in Land Raider armour. Although it's possibly some form of dilatant plastic, that hardens under impacts, which would explain why it was in flak armour.
While I'm at this, I'll bring up Ceramite. Little explanation is needed - some form of hard and heat resistant ceramic.
Prometheum differs from real-world petrol (or whatever you put in flamethrowers) because it ignites on contact with air, thus not needing a starter light at the nozzle.
They're inconsistent about that, and rightly so, as it's explicitly explained that promethium is just a generic term the fuel used in flamer weapons.
Personally, I think it's a bloody stupid idea to use such a self-igniting fuel - very dangerous (I can see obscene numbers of friendly casualties from filling mistakes, ruptured tanks...), and completely unnecessary.
Anyway, I personally see it as (usually, with regard to the original caveat) petrol that's modified or in some other way not suitable for vehicle use. But not all of it is - some may be self igniting, some may just be straight petrol, some may be modified petrol, some may be like napalm... lots of options.
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In general, I work on the principle that the 40k periodic table is the same as ours in most respects, but that some elements have different names. It would be somewhat absurd for Einsteinium & Nobelium to got by those names in their universe for example.
So for example, the element we call Promethium (#61), wouldn't go by that name in their universe.